Investigating the effect of andalusite on mechanical strength and thermal shock resistance of cordierite-spodumene composite ceramics

Abstract

For increasing working stability of cordierite-spodumene composite ceramics for solar heat transmission pipeline, andalusite was utilized as modified additive to improve mechanical strength and thermal shock resistance of the composite ceramics. The effects of andalusite on densification, mechanical strength, thermal stability, phase composition and microstructure were studied. The experiment results showed that andalusite significantly influenced bending strength and thermal shock resistance of the composite ceramics. Especially, specimen B1 with 5wt% andalusite sintered at 1400°C achieved the best performances. The linear shrinkage, water absorption, apparent porosity, bulk density and bending strength were 5.62%, 0.02%, 0.06%, 2.19gcm−3 and 104.94MPa, respectively. After 30 thermal shock cycles (wind cooling from 1100°C to room temperature), the residual strength of the specimen increased to 110.65MPa, accompanying with −5.44% strength loss rate. The XRD and SEM analysis illustrated that mullite grains with short rod-like shape could prevent crack growth of inter-granular fracture to enhance bending strength of the specimens. Furthermore, the generation of β-spodumene grains with low thermal expansion coefficient after thermal shock improved thermal shock resistance of the composite ceramics. It is considered that the cordierite-spodumene composite ceramics with high densification, good mechanical strength and excellent thermal stability can be a potential material for high temperature thermal transmission pipeline in solar thermal power generation.