Abstract
Searching for lead-free piezoelectric materials with a large piezoelectricity and excellent thermal stability has been a major concern in both scientific research and practical applications. To understand the mechanism of high piezoelectricity and its temperature-dependent behavior in lead-free materials, we focus here on the tetragonal (K,Na,Li)(Nb,Ta)O3 single crystal and investigate the intrinsic d33* along arbitrary directions as well as its evolution with temperature. The synergistic influence of several factors (narrow tetragonal temperature interval, sharp tetragonal-cubic phase transition, and large PS below TC) leads to a strong anisotropy in the d33* profile, while a high d33* is obtained around θ = 45° over a wide temperature range. This work comprehensively reveals the physical mechanism of piezoelectric anisotropy in lead-free materials, which provides vital information to design high-performance lead-free piezoelectric materials through orientation engineering and lattice manipulation, which is expected to benefit a wide range of piezoelectric materials.
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