Abstract
Abstract Ru(II)bpy2Mebpy-CH2CH(OH)CH2-MebpyRh(III)L2 (L = bpy. phen) (1) were newly synthesized. Intramolecular electron-transfer in excited 1 was studied with a time-correlated single photon counting method. In H2O, the excited Ru(II) complex exhibits a biexponential decay. The presence of a slow component suggests that the excited state can be repopulated by thermal activation from the Ru(III)–Rh(II) and the direct process to the ground state lies in the Marcus Inverted region.
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