Internal Corrosion of Warm Formed Aluminum Alloy Automotive Heat Exchangers

Abstract

The objective of this study is to evaluate the effects of sheet temper, forming conditions, and the resultant post-braze microstructure on the corrosion behavior of Al alloy heat exchangers. Accelerated corrosion tests were performed by flowing a corrosive water solution through brazed heat exchanger samples fabricated from O and H24 temper sheet formed between room temperature and 250 °C. Sheet perforations within the brazed samples were found to be concentrated at the coolant channel inlets, due to crevice corrosion, or around other formed features within the coolant channel, which was attributed to erosion corrosion. A clear relationship between corrosion initiation sites and local microstructure was not observed in the accelerated test. Potentiodynamic polarization measurements were performed using the corrosive water solution and sheet samples pre-strained to 4 and 10% and subjected to a simulated brazing heat treatment. The average corrosion current density was the same for the two conditions, but liquid film migration occurred during brazing in the sample strained to 4%, resulting in localized corrosion and greater variability in the polarization measurements. It is concluded that warm forming does not impair the corrosion resistance of H24 temper sheet, but the corrosion resistance of brazed samples fabricated from O temper sheet is altered by warm forming.