Abstract
The first example of an intermolecular carbene–carbene coupling reaction between a Fischer and a Schrock carbene ligand is achieved by coupling of the vinylidene fragment in 1 with the methoxyethylidene ligand in 2. In the resulting red titanacyclic chromium carbene complex 3 the chromium is coordinated in such a way by the methoxy substituent that the bicyclic framework is virtually planar.
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