Abstract

The influence of C60 on fluorescence spectra, UV–visible spectra and photoconductivity of polymethylphenylsilane (PMPS) has been studied. The results show that the photoconductivity of PMPS doped with C60 increases by one order of magnitude. The fluorescence and UV–visible analyses indicate that an intermolecular charge-transfer complex of PMPS and C60 may be formed. Compared with C60-doped PMPS, the C60-linked PMPS displays higher photoconductivity than expected, which may come from the intramolecular charge-transfer process.

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