Intermediate temperature fuel cell with a doped ceria–carbonate composite electrolyte

Abstract

The performance of a composite electrolyte composed of a samarium doped ceria (SDC) and a binary eutectic carbonate melt phase has been examined. This material shows higher ionic conductivity than pure SDC in intermediate temperature region. SDC with different morphologies is obtained by co-precipitation, sol–gel and glycine-nitrate combustion preparation techniques. A tri-layer single cell is prepared with a cost-effective co-pressing and co-sintering technique. It is found that the surface properties of SDC and the electrolyte thickness have a great influence on the fuel cell performance. When the co-precipitated SDC is used as the electrolyte component and CO 2/O 2 gas mixture is adopted as the cathode oxidant gas, a fuel cell with an excellent performance is obtained, which has a peak power output of 1704 mW cm −2 at a current density of 3000 mA cm −2 at 650 °C. The influence of cathode atmosphere is examined with conductivity measurement and fuel cell performance test. The results support the concept of O 2−/H +/CO 3 2− ternary conduction.