Interfacial properties in solid-stabilized emulsions

Abstract

We prepared concentrated monodisperse oil-in-water emulsions stabilized by solid particles. The osmotic resistance, Π, of the emulsions was measured for different oil volume fractions above the random close packing (\(\phi ^*\approx 64{\%}\)). The dimensionless osmotic resistance, Π/(γ/R) (γ being the interfacial tension and R being the undeformed drop radius), was always substantially higher than the corresponding values obtained for surfactant-stabilized emulsions. It can be concluded that droplet deformation in solid-stabilized emulsions is not controlled by the capillary pressure, γ/R, of the non-deformed droplets but rather by σ0/R, σ0 being a parameter characterizing the rigidity of the droplets surfaces. The data can be interpreted considering that the interfacial layers are elastic at small deformations and exhibit plasticity at intermediate deformations. σ0 corresponds to the surface yield stress, i.e. the transition between elastic and plastic regimes. We discuss the origin of the surface behavior considering the strong lateral interactions that exist between the adsorbed solid particles. We propose an independent measurement of σ0 based on the critical bulk stress that produces droplet fragmentation in dilute emulsions submitted to shear. Finally, the bulk shear elastic modulus was measured as a function of φ and confirms many of the features revealed by the osmotic resistance.