Abstract
The results of field emission microscopy investigation of the adsorption and thermal desorption of water deposited on a thermally clean and gold-covered tungsten emitter are presented. The desorption experiments indicate that H 2O molecules dissociate in contact with surfaces of the clean tungsten emitter, but no traces of dissociation of water adsorbed on Au W were found, if only the gold coverage was sufficiently high ( Θ ≥ 2). H 2O is probably adsorbed in two adsorption states on Au W . Water desorption from the first state was carried out in the temperature range 145–155 K with an activation energy of 51.5 ± 1.5 kJ/mol, whereas the desorption from the second state was observed at 220–240 K. Generally, the adsorption of water causes the reduction of the emission current at a constant high voltage, both for W and Au W , but for the second adsorption state in the system H 2O/Au/W a slight increase of the emission current was noticed. The behaviour of water adlayer in the presence of the high electric field is discussed.
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