Abstract

The main aim of this research is to study the complexation of molybdenum(VI) with methyliminodiacetic acid in NaClO4 aqueous solutions at pH = 6.00 and ionic strengths (0.1<I/mol⋅dm−3<1.0) at 25 °C by using potentiometric and UV spectrophotometric measurements in order to obtain thermodynamic stability constants at I=0 mol⋅dm−3. A comparison with previous literature data was made for the stability constants, though few data were available. The stability constants data have been analyzed and interpreted by using extended Debye-Huckel theory, specific ion interaction theory and parabolic model. Finally it might be concluded that parabolic model applies better for this complexation reaction.

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