Abstract
The kinetics and equilibria for the reaction between cyanide and iron(II) phthalocyanine [Fe(pc)](H2pc = phthalocyanine) in dimethyl sulfoxide (dmso) were studied at 25 °C. The complex [Fe(pc)(CN)2]2– is formed in two consecutive pseudo-first-order processes with k2f= 17.5 ± 0.8 dm3 mol–1 s–1 and k3f= 0.20 ± 0.05 dm3 mol–1 s–1, where k2f and k3f are the rate constants for the binding of the first and second cyanide ligands, respectively. The equilbrium constants were fund to be K2= 3.0 × 103 dm3 mol–1 and K3= 5.7 × 102 dm3 mol–1, for the formation of [Fe(pc)(CN)(dmso)]– and [Fe(pc)(CN)2]2–, respectively.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Dalton Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
