Abstract

Phase equilibria in the Tl2S-SnS-PbS quasi-ternary system were studied by differential thermal, X-ray powder diffraction, and microstructural analyses. The following schemes were constructed: the state diagrams of the partially quasi-binary sections Tl4SnS3-Tl4PbS3, PbS-Tl4SnS3, and PbS-Tl2Sn2S3, the isothermal section at 520 K, and the projection of the liquidus surface to the concentration triangle of the Tl2S-SnS-PbS system. The coordinates of invariant points and the boundaries of solid solutions were determined.

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