Abstract
A facile and versatile scheme is demonstrated to fabricate nanoscale resistive switching memory devices that exhibit reliable bipolar switching behavior. A solution process is used to synthesize the copper oxide layer into 250-nm via-holes that had been patterned in Si wafers. Direct bottom-up filling of copper oxide can facilitate fabrication of nanoscale memory devices without using vacuum deposition and etching processes. In addition, all materials and processes are CMOS compatible, and especially, the devices can be fabricated at room temperature. Nanoscale memory devices synthesized on wafers having 250-nm via-holes showed reproducible resistive switching programmable memory characteristics with reasonable endurance and data retention properties. This integration strategy provides a solution to overcome the scaling limit of current memory device fabrication methods.
Highlights
A facile and versatile scheme is demonstrated to fabricate nanoscale resistive switching memory devices that exhibit reliable bipolar switching behavior
Transition metal oxide layers have been synthesized by vacuum deposition systems with annealing processes[6,14,15,16]
The fabrication cost and process time for Resistive random access memory (ReRAM) devices can be effectively reduced since the critical step is a solution process and most device fabrication can be done at room temperature (RT) without any additional oxidation/
Summary
A facile and versatile scheme is demonstrated to fabricate nanoscale resistive switching memory devices that exhibit reliable bipolar switching behavior. Transition metal oxide layers have been synthesized by vacuum deposition systems with annealing processes[6,14,15,16]. A Cu2O layer was reported to be formed by thermal oxidation of a copper film grown on a Si substrate[17,18]. The SiO2 layer was used as the sidewall for device isolation; the Cu2O and top electrode of the memory devices were deposited using ECD and E-beam evaporation.
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