Insights into the role of ·OH generated in Fe2+/CaO2/coal slime system for efficient extracellular polymeric substances degradation to improve dewaterability of sewage sludge

Abstract

The disposal of massive sewage sludge and coal slime is a problem facing municipalities in China. A hypothesis for the co-disposal of sludge and coal slime is proposed to improve dewaterability by utilizing the beneficial role of coal slime as a filter assist and CaO2 enhanced system in this research. Results showed that capillary suction time, specific resistance to filtration and water content decreased dramatically from 49.3 s, 13.2 × 1012 m/kg and 84.85% to 19.1 s, 1.0 × 1012 m/kg and 50.07%, respectively, under the optimal conditions with 0.3/0.1/0.3-Fe2+/CaO2/coal slime g/g DS. The hydroxyl radicals generated in the Fe2+/CaO2 process acted on extracellular polymeric substances (EPS), resulting in a drop in the ratio of α-helix/(β-sheet + random coil) in the secondary structure of EPS proteins and a reduction in the concentration of aromatic proteins and tryptophan-like substances in TB-EPS, thereby enhancing the sludge dewaterability. Furthermore, coal slime as the skeleton building material induced a rise in sludge particle size and contact angle, lowering the hydrophilicity, compressibility of sludge and providing more channels to facilitate water flow. This work verified the promising application prospect of the Fe2+/CaO2/coal slime combined system in the enhancement of sludge dewaterability.