Insights into dual-emitting Eu-doped Mn–organic framework with 1D helical chain SBUs as a ratiometric thermometer for temperature sensing

Abstract

The development and construction of smart luminescent MOF materials are highly desired. For the construction of luminescent MOF with new network and smart responsiveness, the introduction of Ln3+ into porous materials by the post-synthetic modification approach is one of the most effective strategies. Herein, a new anionic Mn–organic framework with 1D helical chain SBUs, [(CH3)2NH2][Mn3(OH)(TATB)2] (SQNU-24, H3TATB = 4,4′,4″-s-triazine-2,4,6-triyltribenzoic acid, SQNU = Shangqiu Normal University), was successfully prepared under a DMF/CH3CN solvent system. Benefitting from the anionic skeleton, high porosity, double-walled structure and 1D helical chain SBUs within SQNU-24, the dual-emitting Eu@SQNU-24 was successfully constructed by a post-synthetic modification approach. This work demonstrates the TATB3− ligand as an “antenna” can effectively sensitize Eu3+ ions. Interestingly, the dual-emitting Eu@SQNU-24 as a ratiometric thermometer exhibits a good temperature-responsive property.