Insight into the anti-corrosion performance of two food flavors as eco-friendly and ultra-high performance inhibitors for copper in sulfuric acid medium

Abstract

2,5-dihydroxy-1,4-dithiane (DDD) and 2,5-dimethy- [1.4] dithiane-2,5-diol (DTDD) two food flavors as environmentally-friendly inhibitors for Cu in 0.5 mol/L H2SO4 media were researched via theoretical calculation and experimental ways. Electrochemical measurement data showed that DDD and DTDD can exhibit high level anti-corrosion feature. The anti-corrosion efficiency of DDD and DTDD were as high as 99.6% and 98.9%, respectively. The atomic force microscope (AFM) and scanning electron microscope (SEM) tests showed that the Cu specimens were immersed in the H2SO4 with 5 mM DDD and DTDD for 30 h at the 298 K, and the Cu specimen surface was still smooth. Besides, the adsorption of DDD and DTDD at the interface of Cu/solution was comply with Langmuir adsorption. Theoretical calculation data showed that DDD exhibit more ascendant anti-corrosion feature than DTDD.