Abstract
The precursor 4,5,9,10-tetrakis(3-methylnaphthalen-2-yl)pyrene is synthesized in solution, sublimed on an Au(111) substrate under ultra-high vacuum conditions and converted into the peri-heptacene molecule by thermal activation via surface-assisted oxidative ring-closure and cyclodehydrogenation reactions. Details of this research can be found in the Communcation by José I. Urgel, Pavel Jelínek, Xinliang Feng, David Écija et al. (DOI: 10.1002/anie.202114983).
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