Abstract

An active hydrogen (*H)-mediated strategy paves a way for enhancing ethanol production from CO2 electroreduction. In their Research Article (e202302096), Xu Xiang, Jing He and co-workers unveil that the increased *H coverage on a layered precursor-derived Cu-based catalyst favors hydrogenation of *HCCOH to *HCCHOH and prioritizes the ethanol pathway, enabling highly efficient and durable production of ethanol. Such a strategy could be of potential use in *H-involved reduction reactions.

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