Abstract
The potential of gas chromatography as a separation method for inorganic compounds (organometallic complexes are excluded) is demonstrated. At temperatures up to 1200 K it is possible to separate a large number of elements as their halides, oxides or hydroxides if an inorganic compound of high melting point and low volatility is used as stationary phase. Examples of isothermal and temperature-programmed separations are given. The influences of temperature, column-length, stationary phase and reactive gas or reactive gas mixture on the separation are discussed.
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