Innovative bactericidal adsorbents containing modified xanthan gum/montmorillonite nanocomposites for wastewater treatment

Abstract

Herein, we reported the preparation of novel antibacterial nanocomposites based on biodegradable polymers. The nanocomposites were applied as capable adsorbent for removing of malachite green (MG) dye, as well as inhibiting of E. coli and S. aureus growth as the most common pollutants for water. The grafted xanthan gum with poly(vinylimidazole) (XG-g-PVI) nanocomposites were synthesized in the presence of different Montmorillonite (MMT) nanoclays concentrations (1%, 3% and 5%). The prepared modified XG nanocomposites were detected through XRD, SEM-EDX, FTIR and TEM. The maximum adsorption MG capacity was determined as 99.99% (909.1 mg/g) in basic medium at 30 °C for 90 min. The adsorption isotherm for removal of MG dye was studied against different models like Langmuir, Freundlich, Temkin, FloryHuggins isotherm models, however, the adsorption results were good fitted with Langmuir isotherm model (R2 = 0.9942). Additionally, various adsorption kinetic models: pseudo-first order, second order, pseudo-second order, and intra-particle diffusion models were studied for adsorption mechanism of MG dye on top of prepared nanocomposite surface. Finally, the antibacterial activity outcomes displayed that the prepared XG-g-PVI/MMT nanocomposites had excellent inhibition growth for bacteria and the antibacterial activity increased abruptly with the increased of MMT nanoclay concentrations.