Abstract

When sample solutions of salts containing eluent ions in the same concentration and pH as the mobile phase are injected into a column, they yield positive injection peaks that are quantitatively related to the sample peak areas. Injection peak areas in anion chromatography are linearly related to the cation concentration of the salts injected. Binary mixtures of salts in the presence of moderate amounts of acid or base can be quantitated by the combination of information from injection and sample peak areas.

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