Inhibition of hydrogen–oxygen/air gaseous detonations using CF3I, H2O, and CO2

Abstract

The ignition of hydrogen-air mixtures can cause intense explosions. To ensure the safe utilization of hydrogen fuel and prevent catastrophic explosion accidents, the inhibiting effect of flame inhibitors must be understood since they have important consequences for hazard analyses. In the present study, the detonability of hydrogen mixtures diluted with CF3I, H2O, CO2, and N2 is investigated using numerical computations. The inhibiting effect of chemically active (CF3I, H2O, and CO2) and chemically inert (N2) diluents on the chemical length and time scales of a ZND detonation structure was studied using a detailed chemical kinetic mechanism for hydrogen oxidation. The inhibition efficiency of a halogenated compound, CF3I, towards quenching of hydrogen-air/oxygen gaseous detonations was also studied. As an additive, CF3I was found to promote detonation at lower concentrations. However, at higher concentrations, CF3I suppresses gaseous detonations by acting as a radical-scavenging agent. In the present study, a given retardant's effectiveness for suppressing a given detonation wave was evaluated for CF3I, H2O, CO2, and N2. The combined suppression effects of CF3I, H2O, and CO2 were also investigated. The efficacy of a composite inhibitor towards the quenching of a detonation wave was also evaluated and compared.