Abstract

We have investigated the Mn3d spectral function in La0.6Sr0.4FeO3(LSFO)∕La0.6Sr0.4MnO3(LSMO) heterointerfaces as well as of La1−xSrxMnO3 films using Mn2p−3d resonant photoemission spectroscopy. The strong enhancement of the Mn3d spectra at the Mn2p−3d threshold enables us to extract the Mn3d spectra of LSMO layers in the vicinity of the interface with the LSFO overlayers. We have found that the spectral intensity of eg↑ states near the Fermi level is gradually reduced with increasing LSFO overlayer thickness and is finally saturated at 5–7ML. The close similarity in reduction of the intensity of the eg↑ states between the LSFO∕LSMO interface and hole-doped LSMO films indicates the occurrence of charge transfer at the interface between the LSMO and LSFO layers.

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