Abstract

AbstractThe infrared spectra of the n‐membered cyclanes (n = 10, 12, 13, 14, 15, 16, 17, 18) have been investigated over the frequency range 1600 to 650 cm−1 at temperatures between − 180° and + 100° C in liquid and solid state and for comparison in solid state pressed in KBr. Furthermore the spectra of the liquids at temperatures about 20° C above the melting points and those of thin crystalline films have been observed in the rocksalt region.

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