Abstract

Abstract Infrared intensities of binary overtones and combinations of CH3Cl and CD3Cl molecules have been measured by the pressure broadening technique. Simplified formulas for the intensities of binary overtone and combination bands of symmetric top molecules were given. Contribution from the mechanical anharmonicity was calculated by use of these equations. Contribution from the electric anharmonicity was estimated by ab initio MO method (4–31 G*). The calculated intensities were compared with the observed values and discussed.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.