Abstract
The infrared emission spectrum of the Rydberg molecule XeH was recorded with the Kitt Peak Fourier transform spectrometer. XeH was made in a hollow cathode discharge of 2·2 torr H2 and 0·1 torr Xe. The 0-0 bands of the C 2Π-B 2Σ+ and the D 2Σ+-C 2Π transitions were observed near 3250 cm−1 and 4420 cm−1, respectively. A rotational analysis provides spectroscopic constants for these states.
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