Abstract
The emission spectrum of germanium monobromide in the 360–420 nm region has been examined at high resolution. Three 0-0 bands at 368.8, 383.8, and 385.1 nm have been rotationally analyzed. It was concluded that the observed band system had arisen from a 4Σ −- X 2Π transition. The GeBr molecular constants for the upper and lower states have been determined for the first time using 4Σ − and 2Π state Hamiltonians with higher order interaction constants and a nonlinear least-squares procedure. The isotopic effects have been studied.
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