Influencing of hydrogeochemical conditions and engineering parameters on phase behaviors and remediation performance of in-situ microemulsion for residual PCE in aquifers

Abstract

In-situ microemulsion has great potential for remediation of chlorinated solvent contaminated aquifers due to its efficient solubilization, and the in-situ formation and phase behaviors of microemulsion is a key factor in determining the remediation performance. However, the role of aquifer properties and engineering parameters on microemulsion in-situ formation and phase transition has been rarely attended. In this work, the influences of hydrogeochemical conditions on in-situ microemulsion phase transition and solubilization ability for tetrachloroethylene (PCE) were explored, and the formation condition, phase transition and removal efficiency for in-situ microemulsion flushing under various flushing conditions were investigated. The results indicated that the cations (Na+, K+, Ca2+) all facilitated the microemulsion phase altering from Winsor I → III → II, whereas the anions (Cl−, SO42−, CO32−) and pH variation (5–9) had no profound influence on phase transition. Besides, the solubilization capacity of microemulsion was enhanced by the pH variation and the cations, which was proportional to the cation concentration of groundwater. The column experiments demonstrated that PCE underwent the phase transition from emulsion to microemulsion and then to micellar solution during the flushing process. The formation and phase transition of microemulsion were mainly related to injection velocity and PCE residual saturation in aquifers. The slower injection velocity and higher residual saturation were profitable to the in-situ formation of microemulsion. In addition, the removal efficiency could achieve 99.29 % for residual PCE at 12 °C, enhancing with the finer porous medium, lower injection velocity and intermittent injection. Furthermore, the flushing system exhibited high biodegradability and weak reagent adsorption onto the aquifer media, presenting a low environmental risk. This study provides valuable information on the in-situ microemulsion phase behaviors and the optimal reagent parameters, facilitating the application of in-situ microemulsion flushing.