Abstract
In this paper, the impact of the crystallite sizes of nickel oxide nanoparticles (NiO NPs) on their efficiency for electrochemical capacitors (EC) has been investigated. NiO NPs were prepared without and with low and high concentrations (0.02[Formula: see text]M and 0.1[Formula: see text]M) of cetyltrimethylammonium bromide (CTAB) using the hydrothermal process that represent NiO, NiO-1, NiO-2, respectively. The crystallite size of NiO, NiO-1, NiO-2 NPs was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analysis. The thermogravimetry/differential thermal analysis (TG/DTA) was used to investigate the thermal observation of as-prepared precursor to transform as NiO NPs. HRTEM revealed spherical seed-like morphologies, which consist of aggregated NiO-1 NPs with an average particle size of 9[Formula: see text]nm. The NiO-1 shows the large specific capacitance value of 168[Formula: see text]Fg[Formula: see text] at a current density of 0.5[Formula: see text]Ag[Formula: see text] compared with other NiO and NiO-2 NPs. The study suggests that the low concentration of surfactant CTAB of NiO NPs plays an important role in supercapacitor applications because of the smaller crystallite sizes of the materials as well as a large number of active sites for faradic reaction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
