Abstract
The rate of C=C bond hydrogenation and the yield of paraffins increase in the order 1-hexene < propylene dimers < propylene trimers < propylene tetramers. The kinetic equation of the reaction was derived on the basis of the Breslow-Heck mechanism. The equation is consistent with the experimental data. The ratio between the rates of hydroformylation and hydrogenation correlates to the polar and steric effects of substituents in olefin molecules.
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