Abstract
We present an electro-optical model of a three-layer phosphorescent OLED which accurately describes the measured current efficiency and transient electroluminescence decay for different biases. Central findings are a bias-dependent emission zone, which influences light outcoupling as well as exciton quenching, and the presence of strong triplet-polaron quenching even at low bias. The measured current efficiency initially increases up to 9 V before it decreases, where the increase is found to be caused by reduced triplet-polaron quenching with holes, while the decrease is caused by a reduced light outcoupling and increased triplet-triplet annihilation. The numerical model allows identifying the individual contributions of the exciton continuity equation and explains the electroluminescence decay, which deviates significantly from a mono-exponential decay due to the dominating influence of exciton generation and quenching after the external bias is removed. • Electro-optical OLED model accurately describes current efficiency roll-off. • Bias-dependent emission zone influences light outcoupling and exciton quenching. • Presence of strong triplet-polaron quenching even at low bias. • Numerical model shows individual contributions of the exciton continuity equation. • Non-mono-exponential EL decay is explained by exciton generation and quenching.
Published Version
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