Abstract
The coordination of Ru II (hedta) - with 5-substituted uracils and uridines (X=F, Cl, Br, I, and COOH as 5-substituents) has been studied by 1 H and 19 F NMR spectroscopy in combination with electrochemical methods (CV, DPP). Characteristic CV/DPP waves for the η 2 -type coordination for Ru(hedta) - , found previously for uridine- and cytidene-related ligands, has been observed in all cases except for X=COOH, which is bound at N-3.
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