Abstract
In this study, we investigated the morphology, structure, magnetic, and magnetocaloric properties of ErCrO3 (ECO) nanoparticles synthesized through two distinct chemical routes: combustion and hydrothermal methods. X-ray diffraction analysis revealed a well-crystallized orthorhombic pbnm phase in both samples. The broader Raman peaks observed in the hydrothermal sample indicate a larger strain of 0.138%, compared to the combustion-derived sample. A significant reduction in the magnetic phase transition temperature was observed for ECO nanoparticles synthesized via the hydrothermal method (117 K) compared to those derived from combustion (∼130 K), which can be attributed to size-induced strain. The hydrothermal ECO samples exhibited a broader temperature span and lower entropy changes compared to the combustion-derived counterparts. Consequently, we observed an improved relative cooling power of 523 J K−1 and entropy change of −10.8 J kg−1 K−1 at a magnetic field of 50 kOe. These findings are promising for magnetic refrigeration applications. The ability to tailor magnetocaloric properties through straightforward synthesis methods underscores their significance in advancing potential applications.
Published Version
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