Influence of slip velocity at the core of a diffuse soft particle and ion partition effects on mobility.

Abstract

Nonlinear effects on the electrophoresis of a soft particle, consisting of a rigid hydrophobic core coated with a diffuse polymer layer (PEL) suspended in an electrolyte medium, are studied. The impact of the ion partitioning effect arising due to the Born energy difference between the PEL and the electrolyte is approximated based on the equilibrium Boltzmann equation, with which the ion distribution and hence, the charge density is modified. The equations describing the electrokinetic transport comprising the Darcy-Brinkman extended Navier-Stokes equations which includes the ion partitioning effect coupled with the modified Nernst-Planck equations and Poisson equations for electric field are solved numerically. The present numerical model for the soft particle compares well with the existing theoretical solutions and experimental results in the limiting cases. A deviation from existing simplified models based on the Boltzmann distribution of ions occurs when the Debye layer polarization, relaxation and the electroosmosis induced by the PEL immobile charge become significant. The hydrophobicity of the inner core strongly influences the nonlinear electrokinetic effects by modifying the Debye layer, electroosmotic flow in the PEL and surface conduction. The results indicate that the ion partitioning can significantly increase the electrophoretic mobility of the soft particle by attenuating the shielding effect. When the Debye layer is in the order of the particle size the hydrophobicity of the core surface and the ion partitioning effect manifest the surface conduction, which implies that the Boltzmann distribution of ions is no longer valid. The core hydrophobicity and ion partitioning effect have influence on the condensation of the PEL immobile charge, which creates a significant impact on the mobility.