Influence of rare earth substitution on structure, photoluminescence emission properties and Judd-Ofelt analysis of ZnS:Eu3+ red phosphors

Abstract

A series of Eu3+ doped ZnS red emitting phosphors were synthesized by conventional low temperature solid state reaction technique. The structural and spectroscopic characteristics of the prepared materials were examined by theoretical and experimental methods. The XRD results confirm the formation of hexagonal structured ZnS material. Similar morphology is obtained from TEM and SEM analysis and the particle size and grain size were calculated. The compositional analysis using EDS confirms the atomic percentage present in the materials. The optical band gap energy of the samples varied from 3.59 to 3.43 eV. The PL emission under excitation 390 nm has greater emission intensity at concentration x = 0.1 in Zn(1-x)S: xEu3+ material. The intense red emission (614 nm) for concentration x = 0.1 have CIE coordinates (0.6090, 0.3905) with color purity 90.41% and CCT 1629.26 K. The site symmetry of Eu3+ ions was explained using PL emission spectra. The intensity parameters Ω2, Ω4 and Ω6, radiative properties like branching ratio (βR), transition radiative parameter (AR), stimulated emission cross section σe, radiative life time (τR) was calculated from Judd-Ofelt theory. The luminescence decay kinetics was analyzed and the life time of material was calculated in millisecond (ms) range. The strong and intense red emission and the improved stimulated emission cross section offer Eu3+ doped ZnS material useful for designing optoelectronic device applications.