Abstract

The different factors affecting the tensile strength of heavy‐metal fluoride glasses are presented. Surface crystals were found to be responsible for the lower fiber strength. The tensile strength of fluoride glass fibers can be increased by controlling the preform surface and drawing in a dry atmosphere. Using lower draw temperature and dual polymeric coatings increases the strength. Finally, phosphate glass overclad on fluoride glass fiber can be used to prevent surface hydrolysis during the drawing process and increases the tensile strength of fibers due to formation of compressive stress on the outside of the glass fiber.

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