Influence of Mg2+, Ti4+ co-doping concentration on the luminescence properties of Y2O2S:Eu3+, Mg2+, Ti4+ nanotube arrays

Abstract

Y(2−0.065−2x)O3: Eu3+0.065, xMg2+, xTi4+ (x=1.0mol%, 1.5mol%, 2.0mol%, 2.5mol%, and 3.0mol%) nanotube arrays were firstly synthesized by the sol–gel template method to serve as the precursors. The red long afterglow phosphor Y2O2S: Eu3+, Mg2+, Ti4+ nanotube arrays were obtained with high yield and purity by calcinating the precursors in CS2 atmosphere at 850°C for 2h. The morphology and optical properties of the composites were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), photoluminescence spectroscopy and long-lasting phosphorescence, respectively. SEM proves that the Y2O2S: Eu3+, Mg2+, Ti4+ nanotube arrays are highly ordered and have uniform size. XRD investigation shows a pure phase of Y2O2S. From the spectrum, the main emission peaks are excited by the 324nm UV excitation, which are ascribed to Eu3+ ions transition from 5DJ (J=0, 1, 2) to 7FJ (J=0, 1, 2, 3, 4). After irradiation by 365nm UV radiation for 10min, the decay time of the Y2O2S: Eu3+, Mg2+, Ti4+ nanoarrays with Mg2+, Ti4+ co-doping concentration at 2.5mol% could last for over 695s (≥1mcd/m2).