Influence of material processing on crystallographic and electrochemical properties of cobalt-free LaNi 4.95Sn 0.3 hydrogen storage alloy

Abstract

The effects of the alloy preparation methods, including the conventional casting, annealing and melt-spinning, on the crystallographic and electrochemical properties of the Co-free LaNi 4,95Sn 0.3 alloy samples were investigated. The results reveal that the as-cast alloy consists of a main phase of CaCu 5-type structure and a little second phase (Sn) with noticeable composition segregation and rather poor cycling stability ( S 200=40.1%). While the annealed and melt-spun alloys are of single CaCu 5-type structure phase with a more homogeneous composition and lower cell volume expansion rate (Δ V/V) on hydriding, and a dramatically improved cyclic stability ( S 200=73.6%–76.2%), although their activation rate, initial capacity and high-rate dischargeability are lowered somewhat. It is found that the decrease in both the electrocatalytic activity and the hydrogen diffusion rate of the annealed and melt-spun alloys is the main cause for their relatively lower high-rate dischargeability, and the improved cycling stability is due to their lower volume expansion on hydriding and more uniform composition.