Abstract
Abstract Photoinduced electron transfer from the triplet excited state of zinc tetramethylpyridylporphyrin to methyl viologen in aqueous solution involves the intermediate formation of a triplet ion pair which can dissociate either to ground state reactants or to redox products. The yield of redox products decreases when the ionic strength of the background electrolyte exceeds 0.1 M and this effect can be explained in terms of a modified Fuoss equation.
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