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Abstract
The influence of change in ion background on the aquation rate constants of [CrCl3(H2O)3)] was studied spectrophotometrically at 25°C over a broad range of ionic strengths (up to several moles/liter). The electrolytes KBr, KCl, NaClO4, NaCl, NaBr, NaNO3, HClO4, HCl, LiClO4, CaCl2, LaCl3, and ethanol were used. It is shown that the rate constant decreases with increasing electrolyte concentration in the electrolytic media (to 0.3 log unit in some of them), while increasing in ethanol media with increasing content of the alcohol.
Published Version
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Schedule a callMore From: Bulletin of the Russian Academy of Sciences Division of Chemical Science
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