Abstract
Kinetic features of radical polymerization of styrene initiated by tert-butyl perbenzoate in the presence of tris(N,N-dimethyldithiocarbamato)cobalt(III) (CoL3) and its adduct with iodine (CoL3 · 2I2) were studied. The optimal concentration ratios of the activators and tert-butyl perbenzoate, providing fast styrene polymerization at 338–368 K, were determined.
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