Abstract
The effect of mechanical deformation on the formation of quasicrystals in Zr57Ti8Nb2.5Cu13.9Ni11.1Al7.5 glassy ribbons has been investigated. The mechanical treatment drastically affects the crystallization behavior and, in particular, suppresses primary quasicrystal formation. However, quasicrystals can be formed by the addition of the appropriate amount of zirconium. This indicates that if a particular short-range order (e.g., icosahedral) is required for quasicrystal formation and if this short-range order is altered during milling, it can be restored by appropriately adjusting the chemical composition.
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