Industrial Scale Testing and Evaluation of Silver Recovery Process

Abstract

In this paper an industrial scale testing and evaluation of a silver recovery process for treating silver-containing materials is presented. The process that is based on the thiourea leaching, followed by silver cementation allows for recovery of the majority of silver as a metallic product. The thiourea leaching was developed specifically for the zinc cake residue, produced from the conventional zinc roast-leaching process at the KCM 2000 AD (Bulgaria), which contains up to 200 g/t silver. The material has a complex zinc ferrite dominated mineralogy with minor zinc hydrosulfate, gypsum, anglesite and plumbojarosite. The feed zinc cake residue is washed with water to remove water soluble zinc by pulping it into 25-30% solids slurry. The washing is carried out in 60 minutes and the resulted slurry is sent to the solid/liquid separation section for filtration. The resulted solids are sent to thiourea leaching and the zinc-containing solution is sent for further zinc recovery. The washed (water-soluble zinc free) solids is pulped into 20% solids slurry. Using thiourea as lixiviant, ferric iron as oxidant, sodium metabisulfite as a reductant and sulfuric acid for pH control, the leaching is performed for 35 minutes at 35oC. Within the leaching process the operating conditions are controlled to allow high silver extraction, while reducing the detrimental effects of thiourea degradation. Silver is recovered from the pregnant leach solution by cementation that results in the formation of a high-grade silver cement product. Iron powder is used as a cementation agent to recover over 94% silver at ambient temperature for 90 minutes. Details of the development work and key process steps are described. The operational data and outcomes of the industrial scale testing are presented along with process performance evaluation.