Abstract

Liquefied petroleum gas (LPG) becomes popular in the twentieth century as source of energy, since it is economically feasible to be produced, transported, sold and stored as a liquid fuel. LPG in Egypt is considered one of the most important domestic fuels. Egypt imports half of its LPG fuel demand. Many researches have been developed to increase the production of LPG in Egypt by increasing the productivity of the refineries. The objective of this study is to investigate the possibility of adding other relatively volatile hydrocarbons as ethane, n-pentane and pentanes’ isomers (iso-pentane and neo-pentane) and/or utilizing relatively volatile oxi-hydrocarbons [mainly dimethyl ether (DME) or dimethyl propane (DMP)] to increase LPG production without affecting its specifications, in order to reduce the import gap of LPG in Egypt. The new LPG mixture is adjusted to meet the Egyptian specifications of LPG (2020). Due to ethane critical properties, it is recommended not to add ethane to LPG since the behavior of ethane cannot be predicted at 50 °C and will be separated inside the LPG bottle. In addition, it will necessitate the increase in LPG butane content. In summer, it is recommended to add i-C5 or 2,2DMP or a mixture of both to LPG (depending on the cost). In winter, it is recommended to add 2,2DMP or a mixture of 2,2DMP with i-C5 to LPG (depending on the cost). Adding DME to LPG with any percentage will decrease the heating value below the Egyptian heating value specifications (2020). Adding neo-pentane to LPG is more preferable than DME, since the heating value of neo-pentane is higher than that of DME. Also, the production cost of the neo-pentane is lower than that of DME.

Highlights

  • Propane and butane are the main components of liquefied petroleum gas (LPG)

  • The objective of this study is to reduce the import gap of LPG in Egypt by increasing the production rate of LPG by utilizing other relatively volatile hydrocarbons as ethane, n-pentane and pentanes’ isomers and/or utilizing relatively volatile oxi-hydrocarbons mainly dimethyl ether (DME)

  • The heating value of LPG after increasing ethane content is still higher than the specified heating value (11,800 kcal/kg)

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Summary

Introduction

Propane and butane are the main components of liquefied petroleum gas (LPG). They can exist as individual components (pure propane or butane). The ratio of propane to butane in LPG depends on the final consumer, whether industrial or commercial use or for domestic purposes (Bilal and Said 2003; Martyr and Plint 2012). The production of LGP follows the agreement with consumers or follow the specifications fixed by the country about the composition (Liang et al 2010). The specifications of LGP are based on the minimum vaporization rate, maximum vapor pressure and the limitation of corrosive components such as sulfur and water (Zakaria et al 2006; Yaws 2015).

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