In Situ Synthesis of Metal-Containing ZSM-5 and Its Catalytic Performance in Aromatization of Methanol.

Abstract

Metal-containing ZSM-5 zeolites, denoted as M/ZSM-5 (M = Ga, Zn, and La), were prepared by an in situ synthetic method. The structural, textural, and surface acid properties of M/ZSM-5 were characterized by XRD, N2 adsorption–desorption, NH3-TPD, and FT-IR. The catalyst pore size and the distribution of strong acid and weak acid were affected by the introduction of metal. Considering the methanol-to-aromatics model reaction, the catalytic performance of these samples was investigated in a fixed bed reactor under the conditions of 450 °C and a liquid weight hourly space velocity (WHSV) of 5 h–1. The results indicated that the Zn/ZSM-5 molecular sieve was most beneficial to aromatization; the relationship between the change of B/L caused by Zn content and aromatics selectivity was further studied. When the B/L value decreased, the selectivity of aromatics showed an initial increase and then a decrease. The B/L value was optimal, and the aromatics yield was the highest when the Zn loading was 0.35%.