Abstract
Antibiotic wastewater has attracted significant attention in recent years. In this study, a novel biochar-based piezocatalyst with a nanoflower structure was synthesized using a method involving the in situ growth of ZnO on a Yang flocculant. The piezoelectric degradation rate of tetracycline was 89.07% after 20 min, and the first-order kinetic constant was 0.682 min−1. Density functional theory calculations showed that the high catalytic activity of ZnO@YCF resulted from its excellent electron transport ability. Radical quenching and electron paramagnetic resonance results showed that OH and O2− radicals were the main radicals involved in TC degradation, with contributions of 58.78% and 37.39%, respectively. A possible TC degradation pathway was proposed based on intermediate studies. Moreover, aquatic toxicity migration was evaluated during the TC degradation process using an ecological structure–activity relationship model. This study proposes a new concept and an efficient way to reuse biomass waste.
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