Abstract

We report photoelectron emission microscope observations of the thermal martensitic transformation in a CuZnAl shape memory alloy. The phase transformation appears at 48°C during heating and at 42°C upon cooling. The transformation is marked by a sharp change in photoelectron intensity, as well as a significant displacement and reorientation of surface features. The difference in the photoelectron intensity before and after the transformation is attributed to a change in work function of about 0.2eV. Photoemission electron microscopy provides real-time information on microstructural changes and phase-dependent electronic properties.

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