In-situ photo-crosslinkable elastomer based on polyalphaolefin/halloysite nanohybrid

Abstract

In this research, new injectable and in situ photocurable elastomeric nanohybrids have been fabricated from polyalphaolefin (PAO) resins and halloysite nanofiller. In this regard, the co-oligomerization of long α-olefin monomers (C6, C8 and C10) with alkenol counterparts was carried out via a simple cationic route to provide OH-functionalized PAOs. The newly formed PAO type copolymer resins as well as halloysite nanoclay were then equipped with photocurable CC bonds containing an acrylate moiety. After the characterization of the final chemical substances and also of the intermediate structures, experimentally and computationally by means of Density Functional Theory (DFT) calculations, the neat treated PAO and PAO/halloysite nanohybrids were subjected to a curing process by visible light irradiation (λ ∼ 475 nm, blue light). The crosslinking efficiency of the neat resins and the formed nanohybrid was evaluated using shrinkage strain–time curves and equilibrium swelling method. The suggested nanohybrid is not only biocompatible (96 % in the MTT assay), and hydrophilic (with a water contact angle of 61°), but also exhibits an easy, fast and robust curing process with great potential for coating and sealing technologies for medical devices.