In Situ Oxidation of Pyridyl-Dihydrobenzoimidazoquinazoline and the Synthesis of a Highly Luminescent Cd(II) Coordination Polymer: A Promising Candidate for Mutagenic Nitroaromatic Detection and Device Fabrication.

Abstract

Pyridyl-substituted imidazoquinoline, a potent fluorescent framework, is advantageous to architect multifunctional coordination networks for sensing and fabricating emergent electrical conductors. In this work, a Cd(II)-based one-dimensional (1D) coordination polymer (1D CP), [Cd(glu)2(pbiq)2(H2O)]n (1), [H2glu = glutaric acid and pbiq = 4-(6-(pyridin-4-yl)benzo[4,5]imidazo[1,2-c]quinazoline)], has been structurally confirmed by single-crystal X-ray crystallography. The H-bonding and π···π interactions built a three-dimensional (3D) supramolecular structure that strongly emits at 416 nm in acetonitrile suspension. Potentially intrusive nitroaromatics (NAs) and trinitrophenol (TNP) selectively quench the strong emission of 1, and the highest quenching is noted in the case of TNP. A detection limit (limit of detection (LOD)) of 1.51 × 10-7 M for TNP is determined. The band gap (3.31 eV) of 1 recognizes semiconducting behavior, and an electronic device is fabricated. The correlation of current vs voltage (I-V plot) reveals a substantial non-ohmic electrical conductivity of 1 (Λ: 1.10 × 10-5 S m-1) along with a low energy barrier (ΦB: 0.69), and the series resistance (Rs) becomes 6.21 kΩ.