Abstract
The local structure around gallium of 0.5, 1 and 5 at.% in liquid silicon at 1440° C has been investigated by the extended X-ray absorption fine structure (EXAFS). The amplitude of EXAFS oscillations is distinct for the very dilute case of 0.5 at.% gallium. The EXAFS analysis shows that the structural parameters of Ga–Si pairs change from 2.8 atoms at a distance of 2.36 Å to 2.1 atoms at a distance of 2.43 Å with increasing gallium content in liquid silicon. These results suggest that a certain local structure around gallium in liquid silicon is formed at low gallium content and that this structural feature disappears with increasing gallium content.
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